| 11. | Its palladium complexes exhibit high activity for Buchwald-Hartwig amination reactions involving aryl chlorides and aryl tosylates.
|
| 12. | Alternatively acetamide can be obtained in excellent yield via ammonolysis of acetylacetone under conditions commonly used in reductive amination.
|
| 13. | Many alkyl amines are produced industrially by the amination of alcohols using ammonia in the presence of acid catalysts.
|
| 14. | Through reductive amination, the sugars are directly conjugated to the protein carrier CRM 197 to form the glycoconjugate.
|
| 15. | Owing to the carcinogenicity of the amine, these derivatives are mainly prepared by amination of the corresponding naphthols.
|
| 16. | JohnPhos is particularly an effective ligand for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates.
|
| 17. | When the amine is used as an electrophile, the reaction is called "'electrophilic amination " '.
|
| 18. | Additional reactions include aldol reactions, Mannich reaction, Michael reaction, amination, ?-oxyamination, and ?-halogenation.
|
| 19. | The reaction between amines and alkyl halogenides is hard to control, making alternative routes ( for instance reductive amination ) more attractive.
|
| 20. | It was originally prepared from tetramethylthiourea via " S "-methylation and amination, but alternative methods start from cyanogen iodide.
|
