| 11. | After excitation, CO 2 coordinates or otherwise interacts with the inner coordination sphere of the reduced metal.
|
| 12. | The first was that Werner described the two different ion possibilities in terms of location in the coordination sphere.
|
| 13. | A noteworthy feature of organorhenium chemistry is the coexistence of oxide and organic ligands in the same coordination sphere.
|
| 14. | WS 2 adopts a layered structure related to MoS 2, with W atoms situated in trigonal prismatic coordination sphere.
|
| 15. | These reactions often do not directly break any metal-ligand bonds, but occur in the second coordination sphere.
|
| 16. | The coordination sphere of RuCl 2 ( PPh 3 ) 3 can be viewed as either five-coordinate or octahedral.
|
| 17. | These eight oxygen atoms surrounding the ion are nearly equidistant from it and adopt a nearly cubic coordination sphere around the ion.
|
| 18. | This means that large structural rearrangements or dramatic changes to the coordination sphere are unlikely to be involved in the catalytic mechanism.
|
| 19. | The magnesium coordination sphere involves the same aspartate along with five water molecules, one of which is shared with the zinc molecule.
|
| 20. | The disproportionation is most likely catalyzed in the second coordination sphere, but the mechanism of electron transfer is still up for debate.
|
