Initial synthetic applications of protodeboronation were found alongside the discovery of the hydroboration reaction, in which sequential hydroboration-protodeboronation reactions were used to convert alkynes or alkenes into the corresponding saturated compounds.
12.
Initial synthetic applications of protodeboronation were found alongside the discovery of the hydroboration reaction, in which sequential hydroboration-protodeboronation reactions were used to convert alkynes or alkenes into the corresponding saturated compounds.
13.
One mechanistic study has revealed a variety of protodeboronation pathways in aqueous media, and displays the reaction pH ( and subsequently the boronic acid speciation ) to be an important factor in understanding the modes of protodeboronation.
14.
One mechanistic study has revealed a variety of protodeboronation pathways in aqueous media, and displays the reaction pH ( and subsequently the boronic acid speciation ) to be an important factor in understanding the modes of protodeboronation.
15.
The deliberate protodeboronation of boron acids ( and derivatives ) have been applied to some synthetic procedures, such as the installation of a stereospecific proton at chiral centers, and also in purification procedures, such as and the removal of unwanted regioisomeric boronic acid by-products.
