The range of possible thermometric titration applications far exceeds the actual experience of this writer, and the reader will be referred to the appropriate literature in some instances.
12.
Figure 6 illustrates a modern automated thermometric titration system based on the Metrohm 859 Titrotherm interface module with Thermoprobe sensor, Metrohm 800 Dosino dispensing devices and a computer running the operational software.
13.
In thermometric titrations, a constant addition rate of titrant equates to a constant amount of heat being given out or consumed, and hence a more or less constant temperature change up to the endpoint.
14.
The suitability of a particular chemical reaction as a candidate for a thermometric titration procedure can generally be predicted on the basis of the estimated amount of analyte present in the sample and the enthalpy of the reaction.