| 11. | That transition state will then be the rate-determining step of a given reaction.
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| 12. | Accordingly, the methyl transition state is very far to the right.
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| 13. | Rearrangements for which a chair transition state is geometrically impossible can nonetheless occur.
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| 14. | I'm also wondering if there any good candidate reactions for cyclic transition states.
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| 15. | This is different than the believed Zimmerman-Traxler model like transition state.
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| 16. | The suprafacial shift is strained transition state and is also unlikely.
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| 17. | The catalyst stabilizes the transition state more than it stabilizes the starting material.
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| 18. | The pericyclic transitions states involving concerted synchronous or concerted asynchronous processes.
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| 19. | Reaction coordinates can then be simulated, and transition state structures solved.
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| 20. | If transition state involves 4n electrons, the Mobius topology is aromatic and allowed.
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