For high vibrational levels, coupling overrides the vibrational relaxation while the contrary is true for the lowest levels, even if a rare gas is involved.
12.
According to a recent study, the reaction can be interpreted as the result of two successive reactions, the second reaction corresponding to a vibrational relaxation through collision using Rg:
13.
Therefore, for some instant during the vibrational relaxation that the ions undergo after the excitement, it is possible for the spin to flip with little or no energy required in the transition.
14.
In 1989, she received her Habilitation at the Lodz University of Technology for her work " Mechanisms of vibrational relaxation in the H-bonded complexes and in conformationally mobile molecules in liquid solutions ."
15.
A . El-Sayed in the 1960s, this rule found in most photochemistry textbooks is useful in understanding phosphorescence, vibrational relaxation, intersystem crossing, internal conversion and lifetimes of excited states in molecules.
16.
It is adequately comparable with a direct measure which is 0.087 ?0.009 . This relation is important because it plays an important role in the vibrational relaxation of states B and C.
17.
Since most of the time XeCl ( B, C ) is formed with a strong vibrational excitation, knowledge of the exact estimate of the variation of k and k with v; and the chemical kinetics of the vibrational relaxation and its importance relative vis-?vis to the coupling process are important.
