In the field of chemical kinetics, he proposed the Lindemann mechanism in 1921 for unimolecular chemical reactions, and showed that the first step is one of bimolecular activation.
22.
An alternative method to detecting protein protein proximity is the bimolecular fluorescence complementation ( BiFC ), where two parts of a fluorescent protein are each fused to other proteins.
23.
"' Bimolecular fluorescence complementation "'( also known as "'BiFC "') is a technology typically used to validate protein interactions.
24.
Aryl methyl ethers ( as well as activated primary alkyl ethers ), on the other hand are dealkylated through a bimolecular mechanism involving two BBr 3-ether adducts.
25.
In practical bimolecular simulations one can often speed-up conformational search significantly ( up to 100 times in some cases ) by using much lower collision frequency \ gamma.
26.
Because it involves the collision of two NO 2 molecules, it is a bimolecular reaction with a rate law of r = k [ NO _ 2 ] ^ 2.
27.
For example, kinetic isotope effects can be used to reveal whether a nucleophilic substitution reaction follows a unimolecular ( S N 1 ) or bimolecular ( S N 2 ) pathway.
28.
Association with TAP is an ATP-independent event, in a fast bimolecular association step, peptide binds to TAP, followed by a slow isomerisation of the TAP complex.
29.
The Terrence Donnelly Centre for Cellular and Bimolecular Research facility received the 2006 Royal Institute of British Architects ( RIBA ) International Award and the 2006 Ontario Association of Architects Award of Excellence.
30.
The rate of the S N 2 reaction is second order overall due to the reaction being bimolecular ( i . e . there are two molecular species involved in the rate-determining step ).