For reductive elimination to occur the two groups ( X and Y ) should be mutually adjacent on the metal's coordination sphere.
22.
The coordination sphere of this ion thus consists of a central MN 6 core " decorated " by 18 N-H bonds that radiate outwards.
23.
Phosphate centers pendant on the cofactor are bound to a Mg 2 +, which is also bound by Asn93 and Ala183 to complete its octahedral coordination sphere.
24.
The mechanism of such reactions often invoke ion-pairing of the entering anion in the second coordination sphere followed by dissociation of the aquo ligand ] ].
25.
The central three-coordinate lithium atom is not bonded to PMDTA . One of the terminal Li centers is pseudo-tetrahedral in an N 4 coordination sphere.
26.
Every tungsten atom is covalently bonded to six selenium ligands in a trigonal prismatic coordination sphere, while each selenium is bonded to three tungsten atoms in a pyramidal geometry.
27.
The coordination sphere of the metal ligands sterically influences which end of the propylene attaches to the growing polymer chain and the relative stereochemistry of the methyl groups on the polymer.
28.
This interest is motivated by the inclusion of high field ligands like cyano and CO ( metal carbonyl ) in the first coordination sphere of the pertinent di-iron cluster.
29.
In hexamminecobalt ( III ) chloride ( [ Co ( NH 3 ) 6 ] Cl 3 ), the cobalt cation plus the six ammonia ligands comprise the first coordination sphere.
30.
In aqueous solution the water molecules directly attached to the metal ion are said to belong to the first coordination sphere, also known as the first, or primary, solvation shell.
