The resulting sodium salt of 1-( nitromethyl ) cyclohexanol is added to acetic acid and shaken with hydrogen gas in the presence of W-4 Raney nickel catalyst.
22.
The compound "'cyclohexyl nitrite "'is an organic nitrite compound, with formula C 6 H 11 ONO . It is the ester of cyclohexanol and nitrous acid.
23.
In that study, oxidation of cyclohexane with iodosylbenzene catalyzed by Mn ( TPP ) Cl afforded a 2.5 : 1 mixture of cyclohexanol and cyclohexyl chloride in a total 70 % yield.
24.
Cyclohexenone was accidentally found to be an " in-vitro " catalyst for a relatively mild decarboxylation of t-butyl peroxide as a catalyst for decarboxylation using a solvent choice of cyclohexanol.
25.
"' Isobornyl cyclohexanol "'( "'IBCH "') is an organic compound used primarily as a fragrance because of its aroma which is similar to sandalwood oil.
26.
However, the addition of hexamethylphosphoramide to samarium ( II ) bromide that is in tetrahydrofuran will strengthen it enough that it can reduce cyclohexyl chloride to cyclohexanol, at room temperature, within two hours.
27.
Further research showed that 1 % Cyclohexenone in cyclohexanol will decarboxylate most alpha-amino acids, including non-standard ones, with a yield of 80-95 % in a matter of several hours.
28.
They found that cyclohexanol contained cyclohexenone as a natural impurity, which was three times more abundant in the technical grade cyclohexenone compared to the more purified cyclohexanol ( ~ 0.3 % versus ~ 0.1 % ).
29.
They found that cyclohexanol contained cyclohexenone as a natural impurity, which was three times more abundant in the technical grade cyclohexenone compared to the more purified cyclohexanol ( ~ 0.3 % versus ~ 0.1 % ).
30.
For example, ?-caprolactam can be prepared using NHPI from the so-called KA oil ( " ketone-alcohol " oil, a mixture of cyclohexanol and cyclohexanone ) which is obtained during the oxidation of cyclohexane.
