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अंग्रेजी-हिंदी > phosphonium उदाहरण वाक्य

phosphonium उदाहरण वाक्य

उदाहरण वाक्य
21.It is a base, e . g ., for the deprotonation of ketones to form sodium enolates, phosphonium salts to form Wittig reagents, and formamidinium salts to form diaminocarbenes.

22.The concept of in situ activation of the C-OH bond in phosphonium coupling has also been applied to cross coupling reactions of tautomerizable heterocycles and arenols using other types of activating reagents.

23.As the first direct bond formation via C OH bond activation, phosphonium coupling offers a powerful and practical methodology for chemical synthesis that features operational simplicity, functionality compatibility, and broad substrate scope.

24.Ephraim Katzir first used this method to synthesize poly-L-lysine by polymerizing N-carbobenzyloxy-?-N-carboxy-L-lysine anhydride and removing the carbobenzyloxy protecting group with phosphonium iodide.

25.Marvel worked with a wide variety of compounds, including dialkyl mercury, hexa-substituted ethanes, dienynes, alkyl lithium and Grignard reagents, quaternary phosphonium, and ammonium compounds, preparing them and investigating their reactions.

26.Cl 2 adds to PPh 3 to give triphenylphosphine dichloride ( [ PPh 3 Cl ] Cl ), which exists as the moisture-sensitive phosphonium halide, This reagent is used to convert alcohols to alkyl chlorides in organic synthesis.

27.It was subsequently shown by De Deene " et al " in 2002 that other antioxidants could be used in the manufacture of normoxic gels including tetrakis ( hydroxymethyl ) phosphonium chloride, having first been suggested to Baldock by Billingham in 1996.

28."' Georg Wittig "'( June 16, 1897 & ndash; August 26, 1987 ) was a German chemist who reported a method for synthesis of alkenes from aldehydes and ketones using compounds called phosphonium ylides in the Wittig reaction.

29.If Y is nitrogen, the reaction is referred to as the Sommelet Hauser rearrangement; if Y is oxygen, then it is called a 2, 3-Wittig rearrangement ( not to be confused with the well-known Wittig reaction, which involves a phosphonium ylide ).

30.Furthermore, the nitrogen atom may be replaced by a phosphorus, arsenic, or antimony atom ( the heavier nonmetallic pnictogens ), creating a phosphonium ( ) or arsonium ( ) cation that can itself be substituted similarly; while stibonium ( ) itself is not known, some of its organic derivatives are characterised.

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