| 21. | An added tertiary amine like tributylamine forms a 1 : 2 adduct with the diazapyrene and the complex gets dethreaded.
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| 22. | These reactions are generally run in the presence of a weak base, such as sodium carbonate or tertiary amines.
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| 23. | Oxidation of the tertiary amine then occurs and an iminium ion is formed "'5 " '.
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| 24. | Examples, such as bicine and tricine, contain a basic secondary or tertiary amine fragment together with a carboxylic acid fragment.
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| 25. | Human TAAR5 ( hTAAR5 ) is a functional trace amine-associated receptor which acts as an olfactory receptor for tertiary amines.
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| 26. | Tertiary amines are able to react with benzenesulfonyl chloride under a variety of conditions; the test described above is not absolute.
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| 27. | Therefore, for laboratory purposes, " N "-alkylation is often limited to the synthesis of tertiary amines.
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| 28. | This became the basis of what is now known as the Hofmann elimination, a method for converting quaternary amines into tertiary amines.
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| 29. | This reaction is referred to as the blowing reaction and is catalyzed by tertiary amines like bis-( 2-dimethylaminoethyl ) ether.
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| 30. | While primary, secondary, and tertiary amines were stable when distilled at high temperatures under alkaline conditions, the quaternary amine was not.
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