When embedded in bulk crystals or nanostructures, the energies of these excited states will further split under crystal field, generating a series of states with many closely-spaced energies ( Figure 1 ).
32.
In order to explain the adoption of a particular cation distribution in a spinel structure, one must take into account the crystal field stabilization energies ( CFSE ) of the transition metals present.
33.
The general trend is shown by the magenta line which passes through Ca 2 +, Mn 2 + and Zn 2 +, for which there is no stabilization in an octahedral crystal field.
34.
For that organization, he has represented new works by playwrights including Romulus Linney, Maria Irene Fornes, Eduardo Machado, Rosalyn Drexler, Nilo Cruz, Bloolips, Spiderwoman Theater and Crystal Field, Artistic Director of the theater.
35.
For example, Cu II 2 ( OAc ) 4 ( H 2 O ) 2 is almost diamagnetic below room temperature whereas Crystal Field Theory predicts that the molecule would have two unpaired electrons.
36.
The crystal field splitting energy for tetrahedral metal complexes ( four ligands ) is referred to as ? tet, and is roughly equal to 4 / 9? oct ( for the same metal and same ligands ).
37.
LuAG has a relatively small lattice constant in comparison to the other rare earth garnets, which results in a higher density producing a crystal field with narrower linewidths and greater energy level splitting in absorption and emission.
38.
It's been nearly three weeks since a foot of snow covered the Ravens'Crystal Field and forced Franklin Pierce and New Hampshire College to travel to Southern Connecticut State University to play a first-round game in the NCAA tournament.
39.
Crystal field theory describes a number of physical phenomena well but does not describe bonding nor offer an explanation for why " n " s electrons are ionized before ( " n " " 1 ) d electrons.
40.
This was an important factor contributing to the acceptance of crystal field theory, the first theory to successfully account for the thermodynamic, spectroscopic and magnetic properties of complexes of the transition metal ions and precursor to ligand field theory.