To fully understand it, it is necessary to make a close study of the Nernst equation and Goldman equation . talk ) 15 : 43, 26 February 2016 ( UTC)
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Julius Bernstein was also the first to introduce the Nernst equation for resting potential across the membrane; this was generalized by David E . Goldman to the eponymous Goldman equation in 1943.
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The equilibrium potential of a particular ion is usually designated by the notation " E " ion . The equilibrium potential for any ion can be calculated using the Nernst equation.
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Concentration cell methods of chemical analysis compare a solution of known concentration with an unknown, determining the concentration of the unknown via the Nernst Equation or comparison tables against a group of standards.
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Water splitting can be done at higher pH values as well however the standard potentials will vary according to the Nernst equation and therefore shift by-59 mV for each pH unit increase.
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John R . Huizenga says they had misinterpreted the Nernst equation, leading them to believe that there was enough pressure to bring deuterons so close to each other that there would be spontaneous fusions.
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Dividing the equation by to convert from chemical potentials to electrode potentials, and remembering that } }, we obtain the Nernst equation for the one-electron process Ox + e " ?
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This effect is also predicted by the Nernst equation; the particular acid that was used ( citric, hydrochloric, sulfuric, etc . ) doesn't affect the voltage except through the pH value.
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The Nernst equation prediction failed for strongly acid electrolytes ( pH < 3.4 ), when the zinc electrode dissolves into the electrolyte even when the battery is not providing any current to a circuit.
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This is similar in form to the Nernst equation shown above, in that it is based on the charges of the ions in question, as well as the difference between their inside and outside concentrations.