Other important factors include solvent choice, solution pH, steric effects, temperature, and the pressure of hydrogen inside the hydrogenation vessel.
32.
The regioselectivity of allylation mediated by indium in water is dependent on the steric effects of the substituents on both the intermediate and carbonyl.
33.
Also, the reaction rate was affected considerably by steric effects of 2-substituents, with more bulky groups increasing the rate of reaction.
34.
Electrostatic interactions are generally too weak to be considered traditional bonds or are prevented from forming a traditional bond, possibly by a steric effect.
35.
Steric effects of the alkyl substituents on the carbonyl reactant have been shown to affect both the rates and yields of B�chner Curtius Schlotterbeck reaction.
36.
Chad Tolman developed his ligand cone angle theory that developed into the widely accepted electronic and steric effects of ligands on inorganic and organometallic complexes.
37.
Of course, other effects can play a role in this selectivity process, including electronic effects, steric effects, and thermodynamic versus kinetic reaction control.
38.
A special computational procedure was developed to separate electronic and steric effects of an arbitrary group in the molecule and to reveal their influence on structure and reactivity.
39.
The "'Taft equation "'is a resonance effects influence reaction rates, the Taft equation also describes the steric effects of a substituent.
40.
Oftentimes, as with highly substituted dienes or very bulky dienophiles, steric effects can greatly influence " endo " / " exo " selectivity.
