Barrientos'union filed a strike notice after the company served termination papers to 5, 000 of its more than 13, 000 workers.
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The union filed a second strike notice with the labor department Tuesday afternoon charging an illegal lockout, union busting and termination of union officers.
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The players are believed to have voted overwhelmingly in favor of strike action, and strike notices were due to go out to Football League chairmen.
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Unions at three hotels near the venue of APEC meetings in Manila next month also have filed strike notices with the Department of Labor and Employment.
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The teacher's union gave the school board a strike notice in February 2012 complaining about paying for their health insurance and demanding higher raises.
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A strike notice is usually issued to an employer or negotiators after union leadership and participating workers have agreed on the set terms of a strike action.
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"The workers voted to empower the committee to issue a strike notice to Tosco if the offer hasn't changed, " he said.
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"We got tired of reading about strike notices, " said Tom DiBella, a vice president at the Hartford, Connecticut-based Aeltus.
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We are extremely disappointed that while continuing negotiations in good faith in the hope of finding a settlement the PFA decided to issue strike notices without our knowledge,
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"We've said we can withdraw those strike notices at a second if we get a fair and reasonable settlement, " he said.
