Wyckoff s 1922 book, " The Analytical Expression of the Results of the Theory of Space Groups ", contained tables with the positional coordinates, both general and special, permitted by the symmetry elements.
32.
Correlation diagrams are of no use in analyzing the conservation of orbital symmetry in sigmatropic rearrangements as there are, in general, only symmetry elements present in the transition state i . e . no conserved symmetry elements.
33.
Correlation diagrams are of no use in analyzing the conservation of orbital symmetry in sigmatropic rearrangements as there are, in general, only symmetry elements present in the transition state i . e . no conserved symmetry elements.
34.
There is only one conserved symmetry element in this transformation the mirror plane through the center of the reactants as shown to the left . From this we can assign the symmetry of the molecular orbitals of the reactants very simply.
35.
Any crystal which has a mirror plane as one of its symmetry elements has the property that its mirror image ( with any plane as the mirror plane ) can always be superimposed on the original crystal by translation or rotation or both.
36.
Ligands with a C 2 symmetry element have been particularly popular, in part because the presence of such an element reduces the possible binding conformations of a substrate to a metal-ligand complex dramatically ( often resulting in exceptional enantioselectivity ).
37.
But every symmetry element has a unique normal form, in which it is given as a rotation followed ( if necessary ) by a reflection in the plane of that rotation . talk ) 12 : 28, 16 November 2011 ( UTC)
38.
In a "'molecular symmetry group "', the group elements are the symmetry operations ( " not " the symmetry elements ), and the binary combination consists of applying first one symmetry operation and then the other.
39.
Once the point group of the linear molecule is determined and the correlated symmetry is identified, all symmetry element operations associated to that correlated symmetry's point group are performed for each atom to deduce the reducible representation of the 3 " N"
40.
Rhodocene exists as [ Rh ( C 5 H 5 ) 2 ], a paramagnetic 19-valence electron symmetry elements; this experimentally demonstrates that the monomer does possess the typical sandwich structure of a metallocene although the interpretation of the ESR data has been questioned.
