Or is it possible to carry out aldol reactions without decarboxylation ? talk ) 17 : 16, 13 February 2010 ( UTC)
42.
The Mukaiyama aldol reaction and the Sakurai reaction refer to the addition of silyl enol ethers and allylsilanes to carbonyl compounds, respectively.
43.
Key advantage of this reaction over other types of aldol reaction is the selective generation of an enolate in the presence of aldehydes.
44.
The generic fructose bisphosphate aldolase enzyme cleaves a 6-carbon fructose sugar into two 3-carbon products in a reverse aldol reaction.
45.
As a test, maybe you could run the bot against Aldol reaction and Recursion theory, which use very different schemes for citation.
46.
A similar analysis by Heathcock explains the fact that, with simple substrates, there is essentially no diastereoselectivity for the intermolecular Mukaiyama aldol reaction.
47.
An elegant demonstration of the power of asymmetric organocatalytic aldol reactions was disclosed by MacMillan and coworkers in 2004 in their synthesis of differentially protected carbohydrates.
48.
An aldol reaction, for example, is inherently diastereoselective; if the aldehyde is enantiopure, the resulting aldol adduct is diastereomerically and enantiomerically pure.
49.
"' Modified aldol tandem reaction "'is a sequential chemical transformation that combines aldol reaction with other chemical reactions that generate enolates.
50.
In another development the two components of an aldol reaction are combined together with the asymmetric catalyst S-proline in a ball mill in a mechanosynthesis.
