This is achieved through a disproportionation reaction of toluene in which one toluene molecule transfers its methyl group to another one.
42.
The polysilicon dihalides also form from the thermally-induced disproportionation of perhalosilanes ( according to : " x"
43.
The thiolate ligands are key, they tune to reduction potential of the nickel cofactor to the range of superoxide disproportionation.
44.
However, a rare type of fermentation may also involve the disproportionation of inorganic sulfur compounds in certain sulfate-reducing bacteria.
45.
Like the acid, hypobromite salts are unstable and undergo a slow disproportionation reaction to yield the respective bromate and bromide salts.
46.
The Cannizzaro reaction is a competing reaction when two aldehyde molecules react by disproportionation to form the corresponding alcohol and carboxylic acid.
47.
In conventional bulk free radical polymerization, the dispersity is often controlled by the proportion of chains that terminate via combination or disproportionation.
48.
The disproportionation is most likely catalyzed in the second coordination sphere, but the mechanism of electron transfer is still up for debate.
49.
Compounds with oxidation states + 5 ( blue ) and + 6 ( green ) are strong oxidizing agents and are vulnerable to disproportionation.
50.
Any mixture of these both mechanisms can be described by using the value, and the contribution of disproportionation to the overall termination process:
