coordination sphere वाक्य
उदाहरण वाक्य
मोबाइल
- For reductive elimination to occur the two groups ( X and Y ) should be mutually adjacent on the metal's coordination sphere.
- The coordination sphere of this ion thus consists of a central MN 6 core " decorated " by 18 N-H bonds that radiate outwards.
- Phosphate centers pendant on the cofactor are bound to a Mg 2 +, which is also bound by Asn93 and Ala183 to complete its octahedral coordination sphere.
- The mechanism of such reactions often invoke ion-pairing of the entering anion in the second coordination sphere followed by dissociation of the aquo ligand ] ].
- The central three-coordinate lithium atom is not bonded to PMDTA . One of the terminal Li centers is pseudo-tetrahedral in an N 4 coordination sphere.
- Every tungsten atom is covalently bonded to six selenium ligands in a trigonal prismatic coordination sphere, while each selenium is bonded to three tungsten atoms in a pyramidal geometry.
- The coordination sphere of the metal ligands sterically influences which end of the propylene attaches to the growing polymer chain and the relative stereochemistry of the methyl groups on the polymer.
- This interest is motivated by the inclusion of high field ligands like cyano and CO ( metal carbonyl ) in the first coordination sphere of the pertinent di-iron cluster.
- In hexamminecobalt ( III ) chloride ( [ Co ( NH 3 ) 6 ] Cl 3 ), the cobalt cation plus the six ammonia ligands comprise the first coordination sphere.
- In aqueous solution the water molecules directly attached to the metal ion are said to belong to the first coordination sphere, also known as the first, or primary, solvation shell.
- Where Nd 3 + is in fact the solvated ion with several selenium oxychloride molecules coordinated in the first coordination sphere, that is [ Nd ( SeOCl 2 ) m ] 3 +.
- If water-free green chromium ( III ) chloride is dissolved in water, the green solution turns violet after some time as the chloride in the inner coordination sphere is replace by water.
- He claimed that if the ions were to form a chain this would occur outside of the coordination sphere while the ions that bound directly to the metal would do so within the coordination sphere.
- He claimed that if the ions were to form a chain this would occur outside of the coordination sphere while the ions that bound directly to the metal would do so within the coordination sphere.
- One interesting aspect of this type of complexes is the presence of a physical gap in the coordination sphere; i . e ., the ligands are not placed symmetrically around the metal ion.
- The Nb center is bound within a trigonal prismatic Se 6 coordination sphere descr The Se---Se bond lengths are 2.37, 2.48, 2.91 Angstroms.
- If the lone pairs are not stereoactive, they are spread uniformly around the valence shell, if they are stereoactive they are concentrated in one portion of the coordination sphere preventing that portion from forming bonds.
- This property of the ligand can affect the reactivity of the complex by leaving the first coordination sphere of the metal more open, while still having a second coordination sphere environment similar to that of cyclopentadienyl.
- This property of the ligand can affect the reactivity of the complex by leaving the first coordination sphere of the metal more open, while still having a second coordination sphere environment similar to that of cyclopentadienyl.
- As studied in coordination chemistry, metals ( usually transition metals ) exist in solution bound to ligands, In many cases, the coordination sphere defines geometries conducive to reactions either between ligands or involving ligands and other external reagents.
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