correlation diagram वाक्य
उदाहरण वाक्य
मोबाइल
- The full molecular orbital correlation diagram is constructed in by matching pairs of symmetric and asymmetric MOs of increasing total energy, as explained above.
- Correlation diagrams, which connect the molecular orbitals of the reactant to those of the product having the same symmetry, can then be constructed for the two processes.
- This result can either be derived via an FMO analysis based upon the sign of p-orbital lobes of the HOMO of the polyene or with correlation diagrams.
- From a molecular orbital correlation diagram one can construct an electronic state correlation diagram that correlates electronic states ( i . e . ground state, and excited states ) of the reactants with electronic states of the products.
- From a molecular orbital correlation diagram one can construct an electronic state correlation diagram that correlates electronic states ( i . e . ground state, and excited states ) of the reactants with electronic states of the products.
- However, the state ES-1 does not correlate with the state ES-1'as the molecular orbitals do not transform into each other under the symmetry-requirement seen in the molecular orbital correlation diagram.
- These correlation diagrams indicate that only a conrotatory ring opening of 3, 4-dimethylcyclobutene is symmetry allowed whereas only a disrotatory ring opening of 5, 6-dimethylcyclohexa-1, 3-diene is symmetry allowed.
- Correlation diagrams are of no use in analyzing the conservation of orbital symmetry in sigmatropic rearrangements as there are, in general, only symmetry elements present in the transition state i . e . no conserved symmetry elements.
- The ground state ? 1 2 ? 2 2 of 1, 3-butadiene correlates with the ground state ? 2 ? 2 of cyclobutene as demonstrated in the MO correlation diagram above . ? 1 correlates with ? and ? 2 correlates with ?.
- If the ring opening of 3, 4-dimethylcyclobutene were carried out under photochemical conditions the resulting electrocyclization would be occur via a disrotatory mode instead of a conrotatory mode as can be seen by the correlation diagram for the allowed excited state ring opening reaction.
- He also noted that Mulliken had previously attempted to construct a correlation diagram for the possible orbitals of a polyatomic molecule in two different nuclear configurations, and had even tried to use this diagram to explain shapes and spectra of molecules in their ground and excited states.
- Additionally, the correlation diagram for any 4n electrocyclic reaction will resemble the diagram for the 4 electron cyclization of 1, 3-butadiene, while the correlation diagram any 4n + 2 electron electrocyclic reaction will resemble the correlation diagram for the 6 electron cyclization of 1, 3, 5-hexatriene.
- Additionally, the correlation diagram for any 4n electrocyclic reaction will resemble the diagram for the 4 electron cyclization of 1, 3-butadiene, while the correlation diagram any 4n + 2 electron electrocyclic reaction will resemble the correlation diagram for the 6 electron cyclization of 1, 3, 5-hexatriene.
- Additionally, the correlation diagram for any 4n electrocyclic reaction will resemble the diagram for the 4 electron cyclization of 1, 3-butadiene, while the correlation diagram any 4n + 2 electron electrocyclic reaction will resemble the correlation diagram for the 6 electron cyclization of 1, 3, 5-hexatriene.
- "' Walsh diagrams "', often called "'angular coordinate diagrams "'or "'correlation diagrams "', are representations of calculated orbital binding energies of a molecule versus a distortion coordinate ( bond angles ), used for making quick predictions about the geometries of small molecules.
- अधिक वाक्य: 1 2
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