deprotection वाक्य
उदाहरण वाक्य
मोबाइल
- Final removal of the peptide from the linkage occurs simultaneously with side-chain deprotection with anhydrous hydrogen fluoride via hydrolytic cleavage.
- The polymer was created using deprotection, which involves replacing a specific hydrogen atom in the pendant group with an oxygen atom.
- India, consequently, become a country with the highest level of protection for industry and the highest level of deprotection for agriculture.
- As a result, the selective deprotection of polyfunctional molecules becomes possible using MTM ethers as the protective groups for their hydroxyl groups.
- "' Thermolabile Protecting Groups "'( TPGs ) are applied in chemical synthesis when mild deprotection conditions are required.
- Trimethylsilyl iodide followed by methanol can also be used for Boc deprotection, especially where other deprotection methods are too harsh for the substrate.
- Trimethylsilyl iodide followed by methanol can also be used for Boc deprotection, especially where other deprotection methods are too harsh for the substrate.
- Trimethylsilyl iodide is also used for the removal of the Boc protecting group, especially where other deprotection methods are too harsh for the substrate.
- Finally, deprotection of ( + )-catechin and ( " )-epicatechin trimers derivatives gives four natural procyanidin trimers in good yields.
- Finally, the Fmoc method is considered orthogonal, since ?-amino group deprotection is with base, while final cleavage from the resin is with acid.
- The Gabriel reaction has been generalized to include the alkylation of sulfonamides and imides, followed by deprotection, to obtain amines ( see Alternative Gabriel reagents ).
- Full deprotection of 38 by BBr3 and methanol afforded pancratistatin 3 in 12 steps from commercially available pinitol with an overall yield of 2.3 % 20.
- Selective deprotection of "'A "'yields a new molecule which can again be coupled onto the original monomer, thus forming another new generation.
- Because the liberated fluorenyl group is a chromophore, deprotection by Fmoc can be monitored by UV absorbance of the runoff, a strategy which is employed in automated synthesizers.
- In contrast to BOC and Fmoc groups, these have to be stable over the course of peptide synthesis although they are also removed during the final deprotection of peptides.
- Thus, the Fmoc method is orthogonal in two directions : deprotection of any ?-amino group, deprotection of side groups and final cleavage from the resin occur by independent mechanisms.
- Thus, the Fmoc method is orthogonal in two directions : deprotection of any ?-amino group, deprotection of side groups and final cleavage from the resin occur by independent mechanisms.
- "' Orthogonal protection "'is a strategy allowing the deprotection of multiple protective groups one at a time each with a dedicated set of reaction conditions without affecting the other.
- Oligosaccharide synthesis normally consists of four parts : preparation of the glycosyl donors, preparation of the glycosyl acceptors with a single unprotected hydroxyl group, the coupling of them, and the deprotection process.
- Carbamic acids are intermediates in the decomposition of carbamate protecting groups; the hydrolysis of an ester bond produces carbamic acid the evolution of carbon dioxide drives the deprotection reaction forward, yielding the unprotected amine.
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