nitrosyl वाक्य
उदाहरण वाक्य
मोबाइल
- Furthermore, nitrosyl chloride is a powerful oxidizing agent, and oxidation of the alcohols with concomitant chlorination has been observed.
- In the absence of other radical sources or other proximal reactive groups, the alkyl radical recombines with the nitrosyl radical.
- Two series of nitrogen oxohalides are known : the nitrosyl halides ( XNO ) and the nitryl halides ( XNO 2 ).
- In addition the ruthenium in PUREX raffinate forms a large number of nitrosyl complexes which makes the chemistry of the ruthenium very complex.
- :Nitrosyl chloride can also be used to synthesise them from alcohols . talk ) 10 : 59, 28 May 2010 ( UTC)
- Nitrosyl chloride followed by base leads to the oxime 8 which can be reduced to " pinylamine " "'9 " '.
- Nitrosylated ferrous iron is particularly stable, as the binding of the nitrosyl ligand to ferrous iron ( Fe ( II ) ) is very strong.
- The alkyl radical formed after hydrogen atom transfer is susceptible to standard radical reactions when scavengers are present in sufficient excess to outcompete the nitrosyl radical.
- It is used as a method of replacing the nitrosyl from the modified cysteines and thus can serve in research of the redox modification of different proteins.
- However, recombination of the nitrosyl radical with the alkoxyl radical ( a reversal of the homolytic cleavage ) has been shown to proceed without scrambling of isotope labels.
- "' Nitrosonium tetrafluoroborate "', also called "'nitrosyl tetrafluoroborate "', is a chemical compound with the chemical formula NOBF 4.
- Isotopic labeling of the nitrite with 15N has shown the mechanism non- caged and that the nitrosyl radical formed from a given nitrite recombines randomly with other alkyl radicals.
- In addition, both NOS1 and NOS2 have been shown to form ferrous-nitrosyl complexes in their heme prosthetic groups that may act partially to self-inactivate these enzymes under certain conditions.
- One of the few practical methods is spin trapping of nitric oxide with iron-dithiocarbamate complexes and subsequent detection of the mono-nitrosyl-iron complex with electron paramagnetic resonance ( EPR ).
- "' Nitrosylazide "'is a highly unstable nitrogen oxide, chemical formula N 4 O, which can be synthesized via the following reaction of sodium azide and nitrosyl chloride at low temperatures:
- While the synthesis of alkyl nitrites from nitrosyl chloride is known and oft-employed in the context of complex molecule synthesis, the reaction is reversible and the products are in thermodynamic equilibrium with the starting material.
- This intermiediate is trapped by the nitrosyl radical and then isomerizes to give a ?-nitrate ester which, while both acid-and base-stable, can be reduced to the corresponding alcohol under mild conditions.
- The selective activation and functionalization of alkane C H bonds was reported using a tungsten complex outfitted with pentamethylcyclopentadienyl, nitrosyl, allyl and neopentyl ligands, Cp * W ( NO ) ( ? 3-allyl ) ( CH 2 CMe 3 ).
- :: Returning back to Weregerbil's issue, an interesting case is offered by nitrosyl chloride : as a gas it is yellow; as a liquid ( below " 6.4 �C ) it is red .-- Talk 15 : 26, 2 January 2007 ( UTC)
- Nitrite further breaks down in the meat into nitric oxide ( NO ), which then binds to the iron atom in the center of myoglobin's heme group, reducing oxidation and causing a reddish-brown color ( nitrosomyoglobin ) when raw, and the characteristic cooked-ham pink color ( nitrosohemochrome or nitrosyl-heme ) when cooked.
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