transition state वाक्य
उदाहरण वाक्य
मोबाइल
- With a high value, proton transfer in the transition state is almost complete.
- One way that enzymatic catalysis proceeds is by stabilizing the transition state through electrostatics.
- An example of the late transition state is bromination.
- Transition state for the Narasaka Prasad reduction showing the reasons for the observed diastereoselectivity
- An example of the early transition state is chlorination.
- Thus the energy of the transition state is mostly polarization energy of the solvent.
- Correlation diagrams can then be used to predict the height of transition state barriers.
- Transition state theory fails for some reactions at high temperature.
- The formation of this oxyanion hole stabilizes the transition state of the enzyme-catalyzed reaction.
- Nonetheless, cyclic transition states are frequently invoked to interpret diastereoselectivity.
- DFT-determined geometry for the transition state of the above reaction.
- This result is consistent with the 5-membered cyclic transition state.
- The products that is, in order to reach the transition state for the reaction.
- The reaction proceeds through the 6-membered transition state shown below.
- Repulsion between the negative charges would raise the energy value near the transition state.
- Cram s rule explains the stereoselectivity by considering the transition state depicted in figure 3.
- This type of comparison is especially useful because most transition states cannot be characterized experimentally.
- This action stabilizes the enediol intermediate and the other transition states on the reaction pathway.
- Carbocation rearrangement reactions occur through three-center bond transition states.
- It has been shown that the transition state is a planar six member transition state.
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