heteronuclear वाक्य
उदाहरण वाक्य
मोबाइल
- In 1988, Clore was recruited to the National Institutes of Health ( NIH ) Laboratory of Chemical Physics ( National Institute of Diabetes and Digestive and Kidney Diseases ) located in Bethesda, Maryland, where he interacted closely in the late 1980s and early 1990s with NIH colleagues Ad Bax, Angela Gronenborn and Dennis Torchia on the development of multidimensional heteronuclear NMR spectroscopy and a structural biology effort aimed at proteins involved in the pathogenesis of HIV / AIDS . He has remained at the NIH ever since and is currently an NIH Distinguished Investigator and Chief of the Section on Protein NMR Spectroscopy at the NIH . a Fellow of the American Academy of Arts and Sciences, and a Foreign Member of the Academia Europaea ( Biochemistry and Molecular Biology Section ).
- He was among the first to exploit natural abundance long-range 1H-15N heteronuclear shift correlation experiments, those early reports leading to hundreds of published reports that are the subject of multiple reviews and chapters ., More recently, his research interests have also led to the development of unsymmetrical indirect covariance NMR processing methods that have the potential for significant spectrometer time savings when experimental access to hyphenated 2D NMR . These methods also provide access to 13C-15N Heteronuclear Single Quantum Coherence-Heteronuclear Multiple Bond Coherence ( HSQC-HMBC ) correlation data that are experimentally inaccessible at natural abundance, and to HSQC-ADEQUATE correlation plots that allow carbon-carbon connectivity networks of molecules to be mapped without having to resort to the highly insensitive 13C-13C INADEQUATE experiment.
- He was among the first to exploit natural abundance long-range 1H-15N heteronuclear shift correlation experiments, those early reports leading to hundreds of published reports that are the subject of multiple reviews and chapters ., More recently, his research interests have also led to the development of unsymmetrical indirect covariance NMR processing methods that have the potential for significant spectrometer time savings when experimental access to hyphenated 2D NMR . These methods also provide access to 13C-15N Heteronuclear Single Quantum Coherence-Heteronuclear Multiple Bond Coherence ( HSQC-HMBC ) correlation data that are experimentally inaccessible at natural abundance, and to HSQC-ADEQUATE correlation plots that allow carbon-carbon connectivity networks of molecules to be mapped without having to resort to the highly insensitive 13C-13C INADEQUATE experiment.
- He was among the first to exploit natural abundance long-range 1H-15N heteronuclear shift correlation experiments, those early reports leading to hundreds of published reports that are the subject of multiple reviews and chapters ., More recently, his research interests have also led to the development of unsymmetrical indirect covariance NMR processing methods that have the potential for significant spectrometer time savings when experimental access to hyphenated 2D NMR . These methods also provide access to 13C-15N Heteronuclear Single Quantum Coherence-Heteronuclear Multiple Bond Coherence ( HSQC-HMBC ) correlation data that are experimentally inaccessible at natural abundance, and to HSQC-ADEQUATE correlation plots that allow carbon-carbon connectivity networks of molecules to be mapped without having to resort to the highly insensitive 13C-13C INADEQUATE experiment.
- "' Correlation spectroscopy "'is one of several types of two-dimensional nuclear magnetic resonance ( NMR ) spectroscopy or 2D-NMR . This type of NMR experiment is best known by its acronym, COSY . Other types of two-dimensional NMR include J-spectroscopy, exchange spectroscopy ( EXSY ), Nuclear Overhauser effect spectroscopy ( NOESY ), total correlation spectroscopy ( TOCSY ) and heteronuclear correlation experiments, such as HSQC, HMQC, and HMBC . In correlation spectroscopy, emission is centered on the peak of an individual nucleus; if its magnetic field is correlated with another nucleus by through-bond ( COSY, HSQC, etc . ) or through-space ( NOE ) coupling, a response can also be detected on the frequency of the correlated nucleus.
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