internuclear वाक्य
उदाहरण वाक्य
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- For example, there are two rigorously non-bonding orbitals that are occupied in the ground state of the hydrogen fluoride diatomic molecule; these molecular orbitals are localized on the fluorine atom and are composed of p-type atomic orbitals whose orientation is perpendicular to the internuclear axis.
- For dipolar couplings, the principal axis corresponds to the internuclear vector between the coupled spins; for the CSA, it corresponds to the direction with the largest deshielding; for the quadrupolar coupling, it corresponds to the " z "-axis of the electric-field gradient tensor.
- Potential curves of the states B and C intersect adiabatically with a potential curve correlated to + Cl at large internuclear distances : 7.1 nm experimentally and 7.19 nm and 6.3 nm States B and C merging at long-distance, intersect two successive potential curves correlated to + Cl.
- With reference to the potential curves of Figure 3, the potential curves of V ( + RX ) and V ( + RX ) intersect at a greater internuclear distance than 6s states in a region of strong interactions . in the states 6p [ 1 / 2 ] and 6p [ 3 / 2 ].
- In the special case of a homonuclear diatomic molecule, there is an extra symmetry since in addition to the axis of symmetry provided by the internuclear axis, there is a centre of symmetry at the midpoint of the distance between the two nuclei ( the symmetry discussed in this paragraph only depends on the two nuclear charges being the same.
- At large internuclear separations, the gentle slope of the potential well slowly turns the wave packet back, so when the packet returns to the 3-photon gap, the laser intensity is significantly higher and the gap is wide open trapping the wave packet in a bond-hardened state, which lasts throughout the highest intensities ( Fig . 3b ).
- This approximation is valid because the moment of inertia about the internuclear axis is vanishingly small with respect to other moments of inertia in the molecule ( this is due to the very small rotational moments of single atoms, due to the concentration of almost all their mass at their centers; compare also the extremely small radii of the atomic nuclei compared to the distance between them in a diatomic molecule ).
- Vector addition triangle for orbital angular momentum of a diatomic molecule with components of orbital angular momentum of nuclei and orbital angular momentum of electrons, neglecting coupling between electron and nuclear orbital motion and spin-dependent coupling . Since angular momentum "'N "'of nuclei is perpendicular to internuclear vector "'R "', components of electronic angular momentum "'L "'and total angular momentum "'J "'along "'R "'are equal.
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