tertiary amine वाक्य
उदाहरण वाक्य
मोबाइल
- The tertiary amine contained within the quinuclidine can act as a nucleophile that attacks the most electrophilic carbon of the ketene to promote the formation of ?-lactams.
- In the proposed reaction mechanism the base first converts the acid chloride to the ketene, the organocatalyst then introduces chirality through its quininoid tertiary amine, forming a ketene adduct.
- Imipramine, a tertiary amine, affects numerous neurotransmitter systems known to be involved in the etiology of depression, anxiety, ADHD, enuresis and numerous other mental and physical conditions.
- Chiral tertiary amine catalysts are employed for enantioselective MBH reactions . ?-ICD, a cinchona alkaloid derivative, is famous among the quinidine framework-based catalysts in this sense.
- In the Hofmann elimination, treatment of a quaternary ammonium iodide salt with silver oxide produces hydroxide ion, which acts as a base and eliminates the tertiary amine to give an alkene.
- For this reason, use of chlorinated solvents, particularly dichloromethane, may be inadvisable when a tertiary amine is present in a reaction mixture and heating and / or extended reaction times are required.
- In 2013, trimethylamine was identified as a potent full agonist of human TAAR5, a trace amine-associated receptor that is expressed in the olfactory epithelium and functions as an olfactory receptor for tertiary amines.
- On the other hand, it catalyzes the oxidation of alkanes to tertiary alcohols, amides to t-butyldioxyamides, and tertiary amines to ?-( t-butyldioxyamides ) using tert-butyl hydroperoxide.
- Even pyridines, which are considerably less nucleophilic than typical tertiary amines, are reported to react with dichloromethane at room temperature over a period of several days to weeks to give bis ( pyridinium ) methane salts.
- Bis-tris methane is an organic tertiary amine with labile protons having a pKa of 6.46 at 25 �C . It is an effective buffer between the pH 5.8 and 7.3.
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