diabatic वाक्य
उदाहरण वाक्य
मोबाइल
- However strictly diabatic states do not exist in the general case.
- Hence, pseudo-diabatic potentials are synonymous with diabatic potentials.
- Hence, pseudo-diabatic potentials are synonymous with diabatic potentials.
- Air storage can be adiabatic, diabatic, or isothermal.
- The reagents ( Rg and RX ) approach on a covalent diabatic surface.
- The system wavefunction can be represented as a linear combination of the diabatic states:
- Hence, diabatic potentials generated from transforming multiple electronic energy surfaces together are generally not exact.
- This solution is then applied to form the diabatic potential matrix \ mathbf { W }:
- For reasons that will become clear these states will henceforth be referred to as the diabatic states.
- Their formula allows the transition probability between two diabatic potential curves in the neighborhood of an avoided crossing to be calculated.
- A large \ scriptstyle { v _ { LZ } } results in a large diabatic transition probability and vice versa.
- The diabatic transition probability can still be obtained using one of the wide variety of numerical solution algorithms for ordinary differential equations.
- Comparison of the initial conditions used with the values of the state amplitudes following the transition can yield the diabatic transition probability.
- Diabatic representations constructed with different method can yield different results and the reliability of the result relies on the discretion of the researcher.
- Alternatively, one can avoid explicit use of derivative couplings by switch from the adiabatic to the diabatic representation of the potential energy surfaces.
- If it is too small, the system can undergo a diabatic transition to the lower branch of the anticrossing and dissociate via bond softening.
- The contribution from the change of CSF basis is too expensive to evaluate using numerical method, and is usually ignored by employing an approximate diabatic CSF basis.
- When the dissociation is fast and the gap is small, a diabatic transition may occur where the system ends up on the other branch of the anticrossing.
- Solutions are also sought to general problems in which diabatic surfaces take on arbitrary shapes, or additional surfaces are introduced to deal with other manifested chemical features.
- These can be called "'pseudo-diabatic potentials "', but generally the term is not used unless it is necessary to highlight this subtlety.
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