These heterochiral complexes influence the effective stereoinduction of a scalemic catalyst.
2.
The parameter g represents the reactivity of the heterochiral complex relative to the homochiral complexes.
3.
In this scenario, the heterochiral catalyst is relatively more reactive than the homochiral catalyst complexes.
4.
Figure 10 : When the homochiral complexes are more selective and reactive than the heterochiral complexes.
5.
In addition, this heterochiral complex must have a substantially slower rate of reactivity, r RS.
6.
Under the ML 2 model, a ( + )-NLE infers a less reactive heterochiral catalyst.
7.
In order to achieve an asymmetric amplification, there must be a relatively large concentration of the heterochiral complex.
8.
In other words, there is no thermodynamic disadvantage or advantage to the formation of heterochiral complexes at K = 4.
9.
The heterochiral complex, however, forms a racemic product at a different rate constant ( i . e . r RS ).
10.
Since the homochiral complexes react at identical rates, g can then be described as the rate constant corresponding to the heterochiral complex divided by the rate constant corresponding to either homochiral complex.
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