hydrazone वाक्य
उदाहरण वाक्य
मोबाइल
- Specifically, it is the ( 6-Maleimidocaproyl ) hydrazone of doxorubicin.
- The hydrazone then condenses with a further molecule of acetone to produce the azine.
- It is a nitrile and hydrazone.
- The toxins react with pyridoxal 5-phosphate the activated form of pyridoxine and form a hydrazone.
- Next, the oxaziridine gives the hydrazone by azine is hydrolyzed to give hydrazine and regenerate the ketone.
- Salicylaldehyde pyrazole hydrazone ( SPH ) derivatives were found to inhibit the growth of A549 lung carcinoma cells.
- The hydrazone shock and friction; it is a shock explosive so care must be taken with its use.
- With para-tosylate acid added, the hydrazone compounds can be transformed to the corresponding ketones with almost quantitative yields.
- Following internalization, the hydrazone is hydrolyzed within the acidic environment of target cell endosomes and lysosomes to release active cytotoxic drug.
- Retrosynthetic Scheme II indicates that both the aldehyde and the hydrazone used in the Shapiro coupling reaction were synthesized using Diels-Alder reactions.
- When R 3 is OH, the imine is called an oxime, and when R 3 is NH 2 the imine is called a hydrazone.
- The reactants are an aryl diazonium salt obtained from reaction of the corresponding aniline with sodium nitrite and hydrochloric acid and the hydrazone of pyruvic acid.
- The chelation of lithium cation with the methoxy group is one of the most important features of the transition state for Enders'hydrazone alkylation reaction.
- Another early application is the synthesis of unnatural chiral amino acids in a formal reductive amination for example starting from benzophenone and the hydrazone of benzoyl chloride:
- The hydrazone-based bond is stable at neutral pH ( in the blood ), but is rapidly destroyed in the acidic environment of lysosomes of the cell.
- The payload is the chemotherapy drug doxorubicin which is connected with a hydrazone linker to cysteine residues of the Lewis-Y specific ( chimeric ) monoclonal antibody BR96.
- "' Amdro "'is a trade name for a hydramethylnon-based hydrazone insecticide, commonly used in the southern United States for fire ant control.
- In the original Barton publication the reaction was optimized by using a strong guanidine base, the inverse addition of the hydrazone to an iodine solution, and by exclusion of water.
- Hydrazone-based coupling methods are used in medical biotechnology to couple drugs to targeted antibodies ( see ADC ), e . g . antibodies against a certain type of cancer cell.
- However, their subsequent investigations identified that both the disulfide and hydrazone covalent bonds exhibit effective component exchange processes and so present a reliable means of generating dynamic combinatorial libraries capable of thermodynamic templation.
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