hyperconjugation वाक्य
उदाहरण वाक्य
मोबाइल
- However, hyperconjugation can stabilize the positive charge-containing carbon.
- Negative hyperconjugation with the ? * CF bonds enhances this stabilizing interaction.
- However, they interpreted the data differently by taking into account the hyperconjugation stabilization.
- Is this related to inductive effects or hyperconjugation?
- Stereoelectronic effect contains a large variety of subtopics, including anomeric effects and hyperconjugation.
- Computations reveal a dominant stabilizing hyperconjugation effect of 6 kcal / mol per alkyl group.
- However, his analysis involves geminal repulsion absolutely replacing hyperconjugation as a reasonable alternative explanation.
- Hyperconjugation can be used to explain phenomena such as the gauche effect and anomeric effect.
- This was studied in greater detail by Swain but is still explained best by fluoride hyperconjugation.
- The more substituted the carbocation, the more stable it is, due to induction and hyperconjugation.
- The dirhodium ( II ) tetracarboxylate metallocarbene stabilized by ?C-Rh?! ?C = O hyperconjugation.
- It has been shown, however, that hyperconjugation does depend on the solvent in the system.
- His work was a crucial first step to the beginnings of the ideas of hyperconjugation and conjugation effects.
- Of these two models, hyperconjugation is generally considered the principal cause behind the gauche effect in difluoroethane.
- One alternative to the steric hindrance explanation is based on hyperconjugation as analyzed within the Natural Bond Orbital framework.
- To quantify hyperconjugation effect, they designed the following isodesmic reactions in 1-butyne and 1-butene.
- Gronert claims that his model successfully reproduces accepted data without invoking hyperconjugation and can perhaps explain well-established trends.
- An instance where hyperconjugation may be overlooked as a possible chemical explanation is in rationalizing the rotational barrier of ethane.
- The lowering of the LUMO is the result of hyperconjugation between alkyne ? donor orbitals and CF ? * acceptors.
- Some authors also question the validity of this hyperconjugation model based on results from the quantum theory of atoms in molecules.
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