indenyl वाक्य
उदाहरण वाक्य
मोबाइल
- The so-called indenyl effect also describes changes in hapticity in a substitution reaction.
- He lectured across the world on metal complexes of cyclopentadienyl, indenyl, arenes, olefins, and metal carbonyls.
- Metals studied with 2, 2'- bis ( 2-indenyl ) biphenyl include titanium, zirconium, and hafnium.
- Hydrogenation of the arene ring in the indenyl ligand resulted in CO substitution at about half the rate of the cyclopentadienyl compound.
- Veiros conducted a study comparing the rate of substitution on [ ( ? 5-X ) Mn ( CO ) 3 ] where X is cyclopentadienyl, indenyl, fluorenyl, cyclohexadienyl, and 1-hydronaphthalene.
- Mawby and Jones later studied the rate of CO substitution with P ( OEt ) 3 with Fe ( ? 5-C 9 H 7 ) ( CO ) 2 I and Fe ( ? 5-C 5 H 5 ) ( CO ) 2 I and found that both occur by an S N 1 pathway with the indenyl substitution occurring about 575 times faster.
- Subsequent work by Hart-Davis, Mawby, and White compared CO substitution by phosphines in Mo ( ? 5-C 9 H 7 ) ( CO ) 3 X and Mo ( ? 5-C 5 H 5 ) ( CO ) 3 X ( X = Cl, Br, I ) and found the cyclopentadienyl compounds to substitute by an S N 1 pathway and the indenyl compounds to substitute by both S N 1 and S N 2 pathways.
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