Alfred Werner studied the nitro nitrito isomerism ( 1 and 2 ) extensively.
2.
Nitro-nitrito isomerism is common, where the nitrito form is usually less stable.
3.
Nitro-nitrito isomerism is common, where the nitrito form is usually less stable.
4.
The most common are nitro ( bonded from the nitrogen ) and nitrito ( bonded from an oxygen ).
5.
In varying the aforementioned elements, the mononitrosyl, nitrito, and dinitrosyl complexes have been formed in various conditions.
6.
The anion of this yellow-coloured salt consists of a cobalt ( III ) center bound to six nitrito ligands.
7.
The anion of this yellow-coloured salt consists of a cobalt ( III ) center " N "-bonded to six nitrito ligands.
8.
Another contributor to its exothermic decomposition ( inferred from much safer in silico experimentation ) is the ability of silicon in its crystal phase to coordinate to two oxygen nitrito groups in addition to regular coordination to the four carbon atoms.
9.
The red isomer of pentaamminecobalt ( III ) with nitrite is now known to be a nitrito complex, [ Co ( NH 3 ) 5 ( ONO ) ] 2 +; it is metastable and isomerizes to the yellow nitro complex [ Co ( NH 3 ) 5 ( NO 2 ) ] 2 +.
10.
For example, [ Mn ( THF ) ( TC-5, 5 ) ] favors the mononitrosyl complex after adding stoichiometric additions of NO whereas the nitrito complex is the favored tropocoronand product when in the presence of excess NO respectively . [ Fe ( TC-5, 5 ) ] also promotes NO disproportionation when in the presence of excess NO; however, in contrast to Mn, the final product is [ Fe ( NO ) ( TC-5, 5-NO 2 ) ], where the iron retains the nitrosyl and the nitrite becomes bound to the ligand.
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