Vanadium ( V ) forms various peroxo complexes, most notably in the active site of the vanadium-containing bromoperoxidase enzymes.
2.
The diiron cluster moves through to a peroxo intermediate which can then dehydrate the short-lived alcohol intermediate, liberating water.
3.
As peroxo compound, " tert "-Butyl peroxybenzoate contains about 8.16 wt % of active oxygen and has a so-called decomposition of " tert "-butyl peroxybenzoate even in low concentrations.
4.
On the other hand, Nobumasa Kitajima's dinuclear side-on coordinated peroxo model complexes shows ? ( O-O ) of 741 cm " 1 and UV-Vis absorbances at 349 and 551 nm, which agree with the experimental observations for oxyHc.