diradical वाक्य
उदाहरण वाक्य
मोबाइल
- Intense experimental as well as computational investigations have revealed that mechanistically, the vinylcyclopropane rearrangement can be thought of as either a diradical-mediated two-step and / or orbital-symmetry-controlled pericyclic process.
- Carbon atoms with unsatisfied bonds are found in some oxides, such as the diradical C 2 O or : C = C = O; but these compounds are generally too reactive to be isolated in bulk.
- That is very well not the answer either, the only solution to preserving the elemental ratio is to have a diradical, polyethylene is not a diradical . talk ) 22 : 30, 14 March 2012 ( UTC)
- That is very well not the answer either, the only solution to preserving the elemental ratio is to have a diradical, polyethylene is not a diradical . talk ) 22 : 30, 14 March 2012 ( UTC)
- Its the organization and shapes of these "'molecular orbitals "'that gives rise to the particular properties of triplet oxygen, that being that it has a second order bond ( or " double bond " ) and is diradical.
- This is on par with the 20 picometer difference between C-C and C = C ), and with the magnetic properties of ground state ( triplet ) O 2, which is experimentally confirmed to be paramagnetic, as would be expected of a diradical.
- In even more specific context, these can also name the non-radical singlet state, whereas the diradical state is named " propadienediylylidene ", or " propanediyldiylidene ", and the tetraradical state is named " propedienetetrayl " or " propanetetraylylidene ".
- It is true that, in many situations, radicals are often less stable than those situations where there are no unpaired electrons; but not always ( the example of dioxygen is important to consider here ) and can't be handwaved with " but it's a diradical ".
- Despite the fact that the vast majority of Diels Alder reactions exhibit stereospecific, syn addition of the two components, a diradical intermediate has been postulated ( and supported with computational evidence ) on the grounds that the observed stereospecificity does not rule out a two-step addition involving an intermediate that collapses to product faster than it can rotate to allow for inversion of stereochemistry.
- Often, as was done above, the cluster operator includes only singles and doubles ( see CCSD below ) as this offers a computationally affordable method that performs better than Franck-Condon region ), and especially when breaking single-bonds or describing diradical species ( these latter examples are often what is referred to as multi-reference problems, since more than one determinant has a significant contribution to the resulting wave function ).
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