tetrazole वाक्य
उदाहरण वाक्य
मोबाइल
- In the Julia Kocienski olefination the alkylating agent is a tetrazole.
- The delocalization energy in tetrazole is 209 kJ / mol.
- The inhibitors discovered are of a similar scaffold called a tetrazole group.
- Aminoguanidines can also be used as precursors for the synthesis of tetrazole-based energetic materials and drugs.
- N . B There are some alternative ways of making the tetrazole ring however; c . f.
- Additionally, the tetrazole can be designed to be fluorogenic in order to monitor progress of the reaction.
- Photoinduction takes place with a brief exposure to light ( wavelength is tetrazole-dependent ) to minimize photodamage to cells.
- In the above synthesis of tetrazole derivatives, tributyltin azide has been replaced by the less toxic trioctyltin azide and organoaluminium azides.
- Challenges include the presence of endogenous alkenes, though usually cis ( as in fatty acids ) they can still react with the activated tetrazole.
- Some tetrazole derivatives with high energy have been investigated as high performance explosives as a replacement for TNT and also for use in high performance solid rocket propellant formulations.
- The nitrile group is then transformed to a tetrazole by reaction with sodium azide in the presence of aluminum chloride, one of the standard procedures for building that ring.
- One model of airbags made by the Takata Corporation used ammonium nitrate-based gas generating compositions in airbag inflators instead of the more stable, but more expensive compound Tetrazole.
- Other tetrazoles are used for their explosive or combustive properties, such as tetrazole itself and 5-aminotetrazole, which are sometimes used as a component of gas generators in automobile airbags.
- In the following example, recursive SMARTS notation is used to combine acid oxygen and tetrazole nitrogen in a definition of oxygen atoms that are likely to be anionic under normal physiological conditions.
- Sulfur tetrazole radical derived from photolysis of disulfide and carbon radical derived from photolysis of t-butyl peroxide followed by proton abstraction from triethylamineWhen reactivity-selectivity relationships do exist they signify different reaction modes.
- Tetrazole based energetic materials produce high-temperature, non-toxic reaction products such as water and nitrogen gas, and have a high burn rate and relative stability, all of which are desirable properties.
- The SMARTS above would only match the acid hydroxyl and the tetrazole NH . When a carboxylic acid deprotonates the negative charge is delocalised over both oxygen atoms and it may be desirable to designate both as anionic.
- The Tetrazole-alkene photoclick reaction is another dipolar addition that Husigen first introduced about 50 years ago ( ChemBioChem 2007, 8, 1504 . ( 68 ) Clovis, J . S .; Eckell, A .; Huisgen, R .; Sustmann, R . Chem.
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